Alliance is a city in eastern Stark County, Ohio, United States. The population was 21,672 as of the 2020 census. It was established in 1…Alliance is a city in eastern Stark County, Ohio, United States. The population was 21,672 as of the 2020 census. It was established in 1854 by the merger of three smaller communities and was a manufacturing and railroad hub for much of the 20th century. It is associated with the state flower of Ohio, the scarlet carnation, and is known as the "Carnation City". The University of Mount Union, a private liberal arts college established in 1846, is located in Alliance. Partially extending into Mahoning County, the city is part of the Canton–Massillon metropolitan area.
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